Carbene-catalyzed activation of remote nitrogen atoms of (Benz)imidazole-derived aldimines for enantioselective synthesis of heterocycles
A new mode of carbene-catalyzed heteroatom activation and asymmetric reactions is disclosed. The reaction starts with addition of a carbene catalyst to a (benz)imidazole-derived aldimine substrate. Subsequent oxidation and proton transfer lead to the formation of a catalyst-bound triaza-diene as the...
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| Main Authors: | , , , , , , , , , , |
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| 其他作者: | |
| 格式: | Article |
| 語言: | English |
| 出版: |
2021
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| 主題: | |
| 在線閱讀: | https://hdl.handle.net/10356/148222 |
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| 機構: | Nanyang Technological University |
| 語言: | English |