Carbene-catalyzed activation of remote nitrogen atoms of (Benz)imidazole-derived aldimines for enantioselective synthesis of heterocycles

Carbene-catalyzed activation of remote nitrogen atoms of (Benz)imidazole-derived aldimines for enantioselective synthesis of heterocycles

A new mode of carbene-catalyzed heteroatom activation and asymmetric reactions is disclosed. The reaction starts with addition of a carbene catalyst to a (benz)imidazole-derived aldimine substrate. Subsequent oxidation and proton transfer lead to the formation of a catalyst-bound triaza-diene as the...

Full description

Saved in:
Bibliographic Details
Main Authors: Yang, Xing, Xie, Yongtao, Xu, Jun, Ren, Shichao, Mondal, Bivas, Zhou, Liejin, Tian, Weiyi, Zhang, Xinglong, Hao, Lin, Jin, Zhichao, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
Subjects:
Science
Heterocycles
Imines
Online Access:https://hdl.handle.net/10356/148222
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/148222

Similar Items