Asymmetric Brook rearrangement

Asymmetric Brook rearrangement

Although the Brook rearrangement has been discovered over fifty years ago, there remains significant opportunities for chemists to make new discoveries relating to this reaction. Majority of the examples in the literature report Brook rearrangements using racemic starting materials. In this Focus Re...

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Bibliographic Details
Main Authors: Lee, Nicholas, Tan, Choon-Hong, Leow, Dasheng
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2021
Subjects:
Science::Chemistry
Asymmetric Catalysis
Chirality
Online Access:https://hdl.handle.net/10356/150602
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Institution: Nanyang Technological University
Language: English
Description
Summary:Although the Brook rearrangement has been discovered over fifty years ago, there remains significant opportunities for chemists to make new discoveries relating to this reaction. Majority of the examples in the literature report Brook rearrangements using racemic starting materials. In this Focus Review, we highlight asymmetric variants of Brook rearrangements, focusing on enantioselective and enantiospecific examples.

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