Asymmetric Brook rearrangement
Although the Brook rearrangement has been discovered over fifty years ago, there remains significant opportunities for chemists to make new discoveries relating to this reaction. Majority of the examples in the literature report Brook rearrangements using racemic starting materials. In this Focus Re...
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sg-ntu-dr.10356-1506022021-06-07T05:25:54Z Asymmetric Brook rearrangement Lee, Nicholas Tan, Choon-Hong Leow, Dasheng School of Physical and Mathematical Sciences Science::Chemistry Asymmetric Catalysis Chirality Although the Brook rearrangement has been discovered over fifty years ago, there remains significant opportunities for chemists to make new discoveries relating to this reaction. Majority of the examples in the literature report Brook rearrangements using racemic starting materials. In this Focus Review, we highlight asymmetric variants of Brook rearrangements, focusing on enantioselective and enantiospecific examples. Nanyang Technological University We thank Nanyang Technological University (M4011663 and M4080946) for financial support. The frontispiece shows the iconic building of School of Art, Design and Media in NTU. We will like to thank Jimmy F. Chan (@jimchanfc 2017) for giving us his permission to use the photograph. 2021-06-07T05:25:54Z 2021-06-07T05:25:54Z 2019 Journal Article Lee, N., Tan, C. & Leow, D. (2019). Asymmetric Brook rearrangement. Asian Journal of Organic Chemistry, 8(1), 25-31. https://dx.doi.org/10.1002/ajoc.201800585 2193-5807 0000-0001-9823-0258 https://hdl.handle.net/10356/150602 10.1002/ajoc.201800585 2-s2.0-85057985103 1 8 25 31 en M4011663 M4080946 Asian Journal of Organic Chemistry © 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. All rights reserved. |
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Science::Chemistry Asymmetric Catalysis Chirality |
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Science::Chemistry Asymmetric Catalysis Chirality Lee, Nicholas Tan, Choon-Hong Leow, Dasheng Asymmetric Brook rearrangement |
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Although the Brook rearrangement has been discovered over fifty years ago, there remains significant opportunities for chemists to make new discoveries relating to this reaction. Majority of the examples in the literature report Brook rearrangements using racemic starting materials. In this Focus Review, we highlight asymmetric variants of Brook rearrangements, focusing on enantioselective and enantiospecific examples. |
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School of Physical and Mathematical Sciences |
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School of Physical and Mathematical Sciences Lee, Nicholas Tan, Choon-Hong Leow, Dasheng |
| format |
Article |
| author |
Lee, Nicholas Tan, Choon-Hong Leow, Dasheng |
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Lee, Nicholas |
| title |
Asymmetric Brook rearrangement |
| title_short |
Asymmetric Brook rearrangement |
| title_full |
Asymmetric Brook rearrangement |
| title_fullStr |
Asymmetric Brook rearrangement |
| title_full_unstemmed |
Asymmetric Brook rearrangement |
| title_sort |
asymmetric brook rearrangement |
| publishDate |
2021 |
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https://hdl.handle.net/10356/150602 |
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1702431155947569152 |