Synthesis of α-alkynylnitrones via hydromagnesiation of 1,3-enynes with magnesium hydride

A protocol for the synthesis of α-alkynylnitrones from 1,3-enynes has been developed. The process is triggered by hydromagnesiation of 1,3-enynes with magnesium hydride (MgH2), which is prepared in situ through solvothermal treatment of magnesium iodide (MgI2) with sodium hydride (NaH) in tetrahydro...

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Bibliographic Details
Main Authors: Li, Yihang, Ng, Jia Sheng, Wang, Bin, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
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Online Access:https://hdl.handle.net/10356/154828
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Institution: Nanyang Technological University
Language: English