Use of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthates

Use of a benzyl ether as a traceless hydrogen donor in the anti-Markovnikov hydrofunctionalization of alkenes with xanthates

A new protocol for the anti-Markovnikov hydrofunctionalization of alkenyl alcohol O-Bn ethers was developed using xanthates as functionalizing agents in the presence of lauroyl peroxide as a radical initiator and a stoichiometric oxidant. The benzyl group serves as a traceless hydrogen donor in the...

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Bibliographic Details
Main Authors: Hayashi, Hirohito, Kaga, Atsushi, Wang, Bin, Gagosz, Fabien, Chiba, Shunsuke
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Alkene Derivative
Benzyl Derivative
Online Access:https://hdl.handle.net/10356/154849
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/154849

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