Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite

A simple protocol for hydrodebromination and -deiodination of halo(hetero)arenes was enabled by sodium hydride (NaH) in the presence of lithium iodide (LiI). Mechanistic studies showed that an unusual concerted nucleophilic aromatic substitution operates in the present process.

Saved in:

Bibliographic Details
Main Authors:	Ong, Derek Yiren, Tejo, Ciputra, Xu, Kai, Hirao, Hajime, Chiba, Shunsuke
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2022
Subjects:	Science::Chemistry Haloarenes Hydrodehalogenation
Online Access:	https://hdl.handle.net/10356/154861
Tags:	Add Tag No Tags, Be the first to tag this record!
Institution:	Nanyang Technological University
Language:	English

id	sg-ntu-dr.10356-154861
record_format	dspace
spelling	sg-ntu-dr.10356-1548612023-02-28T19:58:56Z Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite Ong, Derek Yiren Tejo, Ciputra Xu, Kai Hirao, Hajime Chiba, Shunsuke School of Physical and Mathematical Sciences Science::Chemistry Haloarenes Hydrodehalogenation A simple protocol for hydrodebromination and -deiodination of halo(hetero)arenes was enabled by sodium hydride (NaH) in the presence of lithium iodide (LiI). Mechanistic studies showed that an unusual concerted nucleophilic aromatic substitution operates in the present process. Nanyang Technological University Accepted version This work was financially supported by Nanyang Technological University (NTU). 2022-01-17T01:44:25Z 2022-01-17T01:44:25Z 2017 Journal Article Ong, D. Y., Tejo, C., Xu, K., Hirao, H. & Chiba, S. (2017). Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite. Angewandte Chemie International Edition, 56(7), 1840-1844. https://dx.doi.org/10.1002/anie.201611495 1433-7851 https://hdl.handle.net/10356/154861 10.1002/anie.201611495 28071853 2-s2.0-85010886912 7 56 1840 1844 en Angewandte Chemie International Edition This is the peer reviewed version of the following article: Ong, D. Y., Tejo, C., Xu, K., Hirao, H. & Chiba, S. (2017). Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite. Angewandte Chemie International Edition, 56(7), 1840-1844, which has been published in final form at https://doi.org/10.1002/anie.201611495. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	Science::Chemistry Haloarenes Hydrodehalogenation
spellingShingle	Science::Chemistry Haloarenes Hydrodehalogenation Ong, Derek Yiren Tejo, Ciputra Xu, Kai Hirao, Hajime Chiba, Shunsuke Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite
description	A simple protocol for hydrodebromination and -deiodination of halo(hetero)arenes was enabled by sodium hydride (NaH) in the presence of lithium iodide (LiI). Mechanistic studies showed that an unusual concerted nucleophilic aromatic substitution operates in the present process.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Ong, Derek Yiren Tejo, Ciputra Xu, Kai Hirao, Hajime Chiba, Shunsuke
format	Article
author	Ong, Derek Yiren Tejo, Ciputra Xu, Kai Hirao, Hajime Chiba, Shunsuke
author_sort	Ong, Derek Yiren
title	Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite
title_short	Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite
title_full	Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite
title_fullStr	Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite
title_full_unstemmed	Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite
title_sort	hydrodehalogenation of haloarenes by a sodium hydride-iodide composite
publishDate	2022
url	https://hdl.handle.net/10356/154861
_version_	1759853379630137344

Hydrodehalogenation of haloarenes by a sodium hydride-iodide composite

Similar Items