Chemo-selective cross reaction of two enals via carbene-catalyzed dual activation

Chemo-selective cross reaction of two enals via carbene-catalyzed dual activation

A dual catalytic chemo-selective cross-coupling reaction of two enals is developed. One enal (without α-substitution) is activated by an NHC catalyst to form an acylazolium enolate intermediate that undergoes Michael-type addition to another enal molecule bearing an alkynyl substituent. Mechanistic...

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Bibliographic Details
Main Authors: Peng, Xiaolin, Xu, Jun, Li, Tingting, Chi, Robin Yonggui, Jin, Zhichao
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Catalysts
Enantioselectivity
Online Access:https://hdl.handle.net/10356/155113
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/155113

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