Reciprocal-activation strategy for allylic sulfination with unactivated allylic alcohols

• Main Authors: Xie, Peizhong, Sun, Zuolian, Li, Shuangshuang, Cai, Xinying, Qiu, Ju, Fu, Weishan, Gao, Cuiqing, Wu, Shisheng, Yang, Xiaobo, Loh, Teck-Peng
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2022
• Subjects: Science::Chemistry; Reciprocal-Activation Strategy; Allylic Sulfination
• Online Access: https://hdl.handle.net/10356/155331
• Institution: Nanyang Technological University

A reciprocal-activation strategy for allylic sulfination with unactivated allylic alcohols was developed. In this reaction, the hydrogen bond interaction between allylic alcohols and sulfinic acids allowed for reciprocal activation, which enabled a dehydrative cross-coupling process to occur under m...