Alkaline-earth metal catalyzed dehydrative allylic alkylation
An alkaline-earth metal catalytic system for environmentally benign allylic alkylation was developed. Allylic alcohols can be utilized directly at room temperature in this transition-metal-free process, producing water as the only byproduct. A variety of allylic compounds, including the ones contain...
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2022
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sg-ntu-dr.10356-1553352022-03-18T02:00:22Z Alkaline-earth metal catalyzed dehydrative allylic alkylation Xie, Peizhong Li, Shuangshuang Liu, Yanan Cai, Xinying Wang, Jinyu Yang, Xiaobo Loh, Teck-Peng School of Physical and Mathematical Sciences Science::Chemistry Alpha-Allylation Phosphoric-Acid An alkaline-earth metal catalytic system for environmentally benign allylic alkylation was developed. Allylic alcohols can be utilized directly at room temperature in this transition-metal-free process, producing water as the only byproduct. A variety of allylic compounds, including the ones containing all-carbonyl quaternary centers, can be obtained with high yields. Ministry of Education (MOE) We gratefully acknowledge the financial support from the National Natural Science Foundation of China (21702108), the Natural Science Foundation of Jiangsu Province, China (BK20160977), the Six Talent Peaks Project in Jiangsu Province (YY-033), the grant from Ministry of Education of Singapore MOE2016-T1-002-043 (RG111/16), and Nanjing Tech University (39837101). 2022-03-18T02:00:22Z 2022-03-18T02:00:22Z 2020 Journal Article Xie, P., Li, S., Liu, Y., Cai, X., Wang, J., Yang, X. & Loh, T. (2020). Alkaline-earth metal catalyzed dehydrative allylic alkylation. Organic Letters, 22(1), 31-35. https://dx.doi.org/10.1021/acs.orglett.9b03730 1523-7060 https://hdl.handle.net/10356/155335 10.1021/acs.orglett.9b03730 31841010 2-s2.0-85077030446 1 22 31 35 en MOE2016-T1-002-043 RG111/16 Organic Letters © 2019 American Chemical Society. All rights reserved. |
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Science::Chemistry Alpha-Allylation Phosphoric-Acid |
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Science::Chemistry Alpha-Allylation Phosphoric-Acid Xie, Peizhong Li, Shuangshuang Liu, Yanan Cai, Xinying Wang, Jinyu Yang, Xiaobo Loh, Teck-Peng Alkaline-earth metal catalyzed dehydrative allylic alkylation |
| description |
An alkaline-earth metal catalytic system for environmentally benign allylic alkylation was developed. Allylic alcohols can be utilized directly at room temperature in this transition-metal-free process, producing water as the only byproduct. A variety of allylic compounds, including the ones containing all-carbonyl quaternary centers, can be obtained with high yields. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Xie, Peizhong Li, Shuangshuang Liu, Yanan Cai, Xinying Wang, Jinyu Yang, Xiaobo Loh, Teck-Peng |
| format |
Article |
| author |
Xie, Peizhong Li, Shuangshuang Liu, Yanan Cai, Xinying Wang, Jinyu Yang, Xiaobo Loh, Teck-Peng |
| author_sort |
Xie, Peizhong |
| title |
Alkaline-earth metal catalyzed dehydrative allylic alkylation |
| title_short |
Alkaline-earth metal catalyzed dehydrative allylic alkylation |
| title_full |
Alkaline-earth metal catalyzed dehydrative allylic alkylation |
| title_fullStr |
Alkaline-earth metal catalyzed dehydrative allylic alkylation |
| title_full_unstemmed |
Alkaline-earth metal catalyzed dehydrative allylic alkylation |
| title_sort |
alkaline-earth metal catalyzed dehydrative allylic alkylation |
| publishDate |
2022 |
| url |
https://hdl.handle.net/10356/155335 |
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1728433400780423168 |