Reversible CO₂ activation by a N-phosphinoamidinato digermyne

Reversible CO₂ activation by a N-phosphinoamidinato digermyne

The N-phosphinoamidinato digermynes [LG̈e–G̈eL] (L = tBu2PNC(Ph)NAr, 4: Ar = 2,6-iPr2C6H3, 5: Ar = Ph) underwent reversible CO2 activation to form [LG̈eOC(O)G̈eL] (6: Ar = 2,6-iPr2C6H3, 7: Ar = Ph). Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through...

Full description

Saved in:
Bibliographic Details
Main Authors: Fan, Jun, Quek, Shina, Yang, Ming-Chung, Zhang, Zheng-Feng, Su, Ming-Der, So, Cheuk-Wai
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Science::Chemistry
Chemical Activation
Carbon Dioxide
Online Access:https://hdl.handle.net/10356/157592
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
id sg-ntu-dr.10356-157592
record_format dspace
spelling sg-ntu-dr.10356-1575922023-02-28T20:06:56Z Reversible CO₂ activation by a N-phosphinoamidinato digermyne Fan, Jun Quek, Shina Yang, Ming-Chung Zhang, Zheng-Feng Su, Ming-Der So, Cheuk-Wai School of Physical and Mathematical Sciences Science::Chemistry Chemical Activation Carbon Dioxide The N-phosphinoamidinato digermynes [LG̈e–G̈eL] (L = tBu2PNC(Ph)NAr, 4: Ar = 2,6-iPr2C6H3, 5: Ar = Ph) underwent reversible CO2 activation to form [LG̈eOC(O)G̈eL] (6: Ar = 2,6-iPr2C6H3, 7: Ar = Ph). Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through compound 5 in the first step, to form CO2, [LG̈eC(Ph)=C(Ph) G̈eL] (8), [LG̈eF] (9) and [LG̈eC6F5] (10), respectively. Ministry of Education (MOE) National Research Foundation (NRF) Submitted/Accepted version C.-W. So. thanks the National Research Foundation Singapore, NRF-ANR (NRF2018-NRF-ANR026 Si-POP) and Ministry of Education Singapore, AcRF Tier 2 (MOE2019-T2-2-129) for the financial support. M.-C. Yang and M.-D. Su acknowledge the National Center for High-Performance Computing of Taiwan for generous amounts of computing time, and the Ministry of Science and Technology of Taiwan for the financial support. 2022-05-15T07:14:36Z 2022-05-15T07:14:36Z 2022 Journal Article Fan, J., Quek, S., Yang, M., Zhang, Z., Su, M. & So, C. (2022). Reversible CO₂ activation by a N-phosphinoamidinato digermyne. Chemical Communications, 58(7), 1033-1036. https://dx.doi.org/10.1039/D1CC05391D 1359-7345 https://hdl.handle.net/10356/157592 10.1039/D1CC05391D 7 58 1033 1036 en NRF2018-NRF-ANR026 Si-POP MOE2019-T2-2-129 Chemical Communications © 2022 The Royal Society of Chemistry. All rights reserved. This paper was published in Chemical Communications and is made available with permission of The Royal Society of Chemistry. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Chemical Activation
Carbon Dioxide
spellingShingle Science::Chemistry
Chemical Activation
Carbon Dioxide
Fan, Jun
Quek, Shina
Yang, Ming-Chung
Zhang, Zheng-Feng
Su, Ming-Der
So, Cheuk-Wai
Reversible CO₂ activation by a N-phosphinoamidinato digermyne
description The N-phosphinoamidinato digermynes [LG̈e–G̈eL] (L = tBu2PNC(Ph)NAr, 4: Ar = 2,6-iPr2C6H3, 5: Ar = Ph) underwent reversible CO2 activation to form [LG̈eOC(O)G̈eL] (6: Ar = 2,6-iPr2C6H3, 7: Ar = Ph). Compound 7 was further reacted with diphenylacetylene and hexafluorobenzene, which proceeded through compound 5 in the first step, to form CO2, [LG̈eC(Ph)=C(Ph) G̈eL] (8), [LG̈eF] (9) and [LG̈eC6F5] (10), respectively.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Fan, Jun
Quek, Shina
Yang, Ming-Chung
Zhang, Zheng-Feng
Su, Ming-Der
So, Cheuk-Wai
format Article
author Fan, Jun
Quek, Shina
Yang, Ming-Chung
Zhang, Zheng-Feng
Su, Ming-Der
So, Cheuk-Wai
author_sort Fan, Jun
title Reversible CO₂ activation by a N-phosphinoamidinato digermyne
title_short Reversible CO₂ activation by a N-phosphinoamidinato digermyne
title_full Reversible CO₂ activation by a N-phosphinoamidinato digermyne
title_fullStr Reversible CO₂ activation by a N-phosphinoamidinato digermyne
title_full_unstemmed Reversible CO₂ activation by a N-phosphinoamidinato digermyne
title_sort reversible co₂ activation by a n-phosphinoamidinato digermyne
publishDate 2022
url https://hdl.handle.net/10356/157592
_version_ 1759852998087933952

Similar Items