Lewis pair polymerization of alkyl methacrylate by amidinato silicon compounds and Tris(pentafluorophenyl)borane

• المؤلفون الرئيسيون: Chia, Cher-Chiek, Li, Yan, Xiao, Longqiang, Yang, Ming-Chung, Su, Ming-Der, So, Cheuk-Wai
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Boranes; Carbene Homologues
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/157594

0.5 mol% of the amidinato disilyne [LSi:]2 (1, L = PhC(NtBu)2) and 1 mol% of B(C6F5)3 cooperatively polymerized methyl methacrylate (MMA) to form poly(MMA) with the H and CH2C(=CH2)COMe end groups (P1, Mn = 3.1 ×103 gmol-1; repeating unit, n = 31; polydispersity index, Đ: 1.55). The catalytic mechan...