Part A: iterative addition of carbon nucleophiles to N,N-dialkyl carboxamides for the synthesis of α-tertiary amines; Part B: asymmetric synthesis of alkylzincs by rhodium-catalyzed enantioselective arylative cyclization of 1,6-enynes with arylzincs
This thesis contains two parts. Part A (Chapters 1 and 2) describes the synthesis of α-tertiary amines by iterative addition of carbon nucleophiles to N,N-dialkyl carboxamides, and Part B (Chapters 3 and 4) describes the rhodium-catalyzed enantioselective arylative cyclization of 1,6-enynes with ary...
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| Format: | Thesis-Doctor of Philosophy |
| Language: | English |
| Published: |
Nanyang Technological University
2022
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| Online Access: | https://hdl.handle.net/10356/159311 |
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| Institution: | Nanyang Technological University |
| Language: | English |