Palladium-catalyzed aerobic oxidative cyclization of N-aryl imines : indole synthesis from anilines and ketones

• المؤلفون الرئيسيون: Wei, Ye, Deb, Indubhusan, Yoshikai, Naohiko
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2013
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/97583; http://hdl.handle.net/10220/11236

We report here an operationally simple, palladium-catalyzed cyclization reaction of N-aryl imines, affording indoles via the oxidative linkage of two C–H bonds under mild conditions using molecular oxygen as the sole oxidant. The process allows quick and atom-economical assembly of indole rings from...