Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides

An ortho-arylation reaction of aromatic imines with aryl chlorides has been achieved using a cobalt–N-heterocyclic carbene catalyst in combination with a neopentyl Grignard reagent. The reaction takes place at room temperature to afford biaryl products in moderate to good yields.

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Bibliographic Details
Main Authors: Gao, Ke, Lee, Pin-Sheng, Long, Chong, Yoshikai, Naohiko
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2013
Online Access:https://hdl.handle.net/10356/97232
http://hdl.handle.net/10220/10610
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Institution: Nanyang Technological University
Language: English