Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides
An ortho-arylation reaction of aromatic imines with aryl chlorides has been achieved using a cobalt–N-heterocyclic carbene catalyst in combination with a neopentyl Grignard reagent. The reaction takes place at room temperature to afford biaryl products in moderate to good yields.
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2013
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sg-ntu-dr.10356-972322020-03-07T12:34:42Z Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides Gao, Ke Lee, Pin-Sheng Long, Chong Yoshikai, Naohiko School of Physical and Mathematical Sciences An ortho-arylation reaction of aromatic imines with aryl chlorides has been achieved using a cobalt–N-heterocyclic carbene catalyst in combination with a neopentyl Grignard reagent. The reaction takes place at room temperature to afford biaryl products in moderate to good yields. 2013-06-25T04:09:56Z 2019-12-06T19:40:26Z 2013-06-25T04:09:56Z 2019-12-06T19:40:26Z 2012 2012 Journal Article Gao, K., Lee, P.-S., Long, C., & Yoshikai, N. (2012). Cobalt-Catalyzed Ortho-Arylation of Aromatic Imines with Aryl Chlorides. Organic Letters, 14(16), 4234-4237. 1523-7060 https://hdl.handle.net/10356/97232 http://hdl.handle.net/10220/10610 10.1021/ol301934y en Organic letters © 2012 American Chemical Society. |
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| description |
An ortho-arylation reaction of aromatic imines with aryl chlorides has been achieved using a cobalt–N-heterocyclic carbene catalyst in combination with a neopentyl Grignard reagent. The reaction takes place at room temperature to afford biaryl products in moderate to good yields. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Gao, Ke Lee, Pin-Sheng Long, Chong Yoshikai, Naohiko |
| format |
Article |
| author |
Gao, Ke Lee, Pin-Sheng Long, Chong Yoshikai, Naohiko |
| spellingShingle |
Gao, Ke Lee, Pin-Sheng Long, Chong Yoshikai, Naohiko Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
| author_sort |
Gao, Ke |
| title |
Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
| title_short |
Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
| title_full |
Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
| title_fullStr |
Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
| title_full_unstemmed |
Cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
| title_sort |
cobalt-catalyzed ortho-arylation of aromatic imines with aryl chlorides |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/97232 http://hdl.handle.net/10220/10610 |
| _version_ |
1681046574324514816 |