Part A: iterative addition of carbon nucleophiles to N,N-dialkyl carboxamides for the synthesis of α-tertiary amines; Part B: asymmetric synthesis of alkylzincs by rhodium-catalyzed enantioselective arylative cyclization of 1,6-enynes with arylzincs

This thesis contains two parts. Part A (Chapters 1 and 2) describes the synthesis of α-tertiary amines by iterative addition of carbon nucleophiles to N,N-dialkyl carboxamides, and Part B (Chapters 3 and 4) describes the rhodium-catalyzed enantioselective arylative cyclization of 1,6-enynes with ary...

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Bibliographic Details
Main Author: Chen, Jiahua
Other Authors: Chiba Shunsuke
Format: Thesis-Doctor of Philosophy
Language:English
Published: Nanyang Technological University 2022
Subjects:
Online Access:https://hdl.handle.net/10356/159311
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Institution: Nanyang Technological University
Language: English
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