Photoinitiated stereoselective direct C(sp²)–H perfluoroalkylation and difluoroacetylation of enamides

• المؤلفون الرئيسيون: Zhao, Kai, Guo, Jing-Yu, Guan, Ting, Wang, Ying-Xue, Tao, Ji-Yu, Zhang, Yu, Zhang, Qing-Hong, Ni, Kun, Loh, Teck-Peng
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2022
• الموضوعات: Science::Chemistry; Photoredox Catalysis; Unactivated Alkenes
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/159997

A photoinitiated perfluoroalkylative coupling of enamides with perfluoroalkyl iodides and a visible-light-induced difluoroacetylation of enamides with ethyl bromodifluoroacetate have been developed, respectively. These transformations allow the efficacious and straightforward incorporation of biolog...