Carbene-catalyzed enantioselective sulfonylation of enone aryl aldehydes: a new mode of breslow intermediate oxidation

A carbene-catalyzed sulfonylation reaction between enone aryl aldehydes and sulfonyl chlorides is disclosed. The reaction effectively installs sulfone moieties in a highly enantioselective manner to afford sulfone-containing bicyclic lactones. The sulfonyl chloride behaves both as an oxidant and a n...

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Bibliographic Details
Main Authors: Deng, Rui, Wu, Shuquan, Mou, Chengli, Liu, Jianjian, Zheng, Pengcheng, Zhang, Xinglong, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2022
Subjects:
Online Access:https://hdl.handle.net/10356/161331
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Institution: Nanyang Technological University
Language: English