Carbene-catalyzed enantioselective sulfonylation of enone aryl aldehydes: a new mode of breslow intermediate oxidation
A carbene-catalyzed sulfonylation reaction between enone aryl aldehydes and sulfonyl chlorides is disclosed. The reaction effectively installs sulfone moieties in a highly enantioselective manner to afford sulfone-containing bicyclic lactones. The sulfonyl chloride behaves both as an oxidant and a n...
Saved in:
Main Authors: | Deng, Rui, Wu, Shuquan, Mou, Chengli, Liu, Jianjian, Zheng, Pengcheng, Zhang, Xinglong, Chi, Robin Yonggui |
---|---|
Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2022
|
Subjects: | |
Online Access: | https://hdl.handle.net/10356/161331 |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Institution: | Nanyang Technological University |
Language: | English |
Similar Items
-
A reaction mode of carbene-catalysed aryl aldehyde activation and induced phenol OH functionalization
by: Chen, Xingkuan, et al.
Published: (2018) -
N-heterocyclic carbene-catalyzed δ-carbon LUMO activation of unsaturated aldehydes
by: Zhu, Tingshun, et al.
Published: (2018) -
Enantioselective sulfonation of enones with sulfonyl imines by cooperative N-heterocyclic-carbene/thiourea/tertiary-amine multicatalysis
by: Chi, Robin Yonggui, et al.
Published: (2014) -
An enantioselective allylation reaction of aldehydes in an aqueous medium
by: Loh, T.-P., et al.
Published: (2014) -
Addition of a carbene catalyst to indole aryl aldehyde activates a remote δ-sp2 carbon for protonation and formal [4+2] reaction
by: Zheng, Pengcheng, et al.
Published: (2020)