N-heterocyclic carbene-catalyzed δ-carbon LUMO activation of unsaturated aldehydes

N-heterocyclic carbene-catalyzed δ-carbon LUMO activation of unsaturated aldehydes

An N-heterocyclic carbene (NHC) catalyzed domino reaction triggered by a δ-LUMO activation of α,β–γ,δ-diunsaturated enal has been developed for the formal [4 + 2] construction of multisubstituted arenes and 3-ylidenephthalide. These two products, formed in a highly chemo- and regioselective manner,...

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Bibliographic Details
Main Authors: Zhu, Tingshun, Mou, Chengli, Li, Baosheng, Smetankova, Marie, Song, Bao-An, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2018
Subjects:
Aldehydes
Carbon
Online Access:https://hdl.handle.net/10356/86653
http://hdl.handle.net/10220/45178
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/86653
http://hdl.handle.net/10220/45178

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