Carbene-catalyzed LUMO activation of alkyne esters for access to functional pyridines

Carbene-catalyzed LUMO activation of alkyne esters for access to functional pyridines

A carbene-catalyzed LUMO activation of a,b-unsaturated alkyne esters is reported. This catalytic process allows for effective reactions of alkyne esters with enamides to synthesize functional pyridines via simple protocols. A previously unexplored unsaturated alkyne acyl azolium intermediate is invo...

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Bibliographic Details
Main Authors: Mou, Chengli, Wu, Jichang, Huang, Zhijian, Sun, Jun, Jin, Zhichao, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2020
Subjects:
Science::Chemistry::Organic chemistry
Pyridines
NHC Catalyst
Online Access:https://hdl.handle.net/10356/138302
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/138302

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