Sterically stabilized end-on superoxocopper(II) complexes and mechanistic insights into their reactivity with O−H, N−H, and C−H substrates
Instability of end-on superoxocopper(II) complexes, with respect to conversion to peroxo-bridged dicopper(II) complexes, has largely constrained their study to very low temperatures. This limits their kinetic capacity to oxidize substrates. In response, we have developed a series of bulky ligands, A...
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Main Authors: | Quek, Sebastian Y., Debnath, Suman, Laxmi, Shoba, van Gastel, Maurice, Krämer, Tobias, England, Jason |
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Other Authors: | School of Physical and Mathematical Sciences |
Format: | Article |
Language: | English |
Published: |
2022
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Subjects: | |
Online Access: | https://hdl.handle.net/10356/163536 |
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Institution: | Nanyang Technological University |
Language: | English |
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