N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions

N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions

The carbon-sulfur (C-S) bond formation reactions enabled by N-heterocyclic carbene (NHC) organocatalysis are systematically summarized in this review. Diverse transformations involving NHC-catalyzed S-esterification, NHC-catalyzed nucleophilic S-conjugate addition, NHC-catalyzed S-addition reactions...

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Bibliographic Details
Main Authors: Lv, Jie, Jin, Zhichao, Wang, Hongling, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2023
Subjects:
Science::Chemistry
Carbon-Sulfur Bond Formation
N-Heterocyclic Carbene
Online Access:https://hdl.handle.net/10356/170452
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Institution: Nanyang Technological University
Language: English
Description
Summary:The carbon-sulfur (C-S) bond formation reactions enabled by N-heterocyclic carbene (NHC) organocatalysis are systematically summarized in this review. Diverse transformations involving NHC-catalyzed S-esterification, NHC-catalyzed nucleophilic S-conjugate addition, NHC-catalyzed S-addition reactions with electrophiles, and C-S bond formations via cooperative NHC/transition metal-catalyzed radical reactions are introduced and discussed. Our own comprehension and perspectives on this highly active research field are also provided at the end of this review.

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