N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions

N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions

The carbon-sulfur (C-S) bond formation reactions enabled by N-heterocyclic carbene (NHC) organocatalysis are systematically summarized in this review. Diverse transformations involving NHC-catalyzed S-esterification, NHC-catalyzed nucleophilic S-conjugate addition, NHC-catalyzed S-addition reactions...

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Main Authors: Lv, Jie, Jin, Zhichao, Wang, Hongling, Chi, Robin Yonggui
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2023
Subjects:
Science::Chemistry
Carbon-Sulfur Bond Formation
N-Heterocyclic Carbene
Online Access:https://hdl.handle.net/10356/170452
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-1704522023-09-12T06:37:30Z N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions Lv, Jie Jin, Zhichao Wang, Hongling Chi, Robin Yonggui School of Physical and Mathematical Sciences Science::Chemistry Carbon-Sulfur Bond Formation N-Heterocyclic Carbene The carbon-sulfur (C-S) bond formation reactions enabled by N-heterocyclic carbene (NHC) organocatalysis are systematically summarized in this review. Diverse transformations involving NHC-catalyzed S-esterification, NHC-catalyzed nucleophilic S-conjugate addition, NHC-catalyzed S-addition reactions with electrophiles, and C-S bond formations via cooperative NHC/transition metal-catalyzed radical reactions are introduced and discussed. Our own comprehension and perspectives on this highly active research field are also provided at the end of this review. Ministry of Education (MOE) National Research Foundation (NRF) We acknowledge funding supports from National Natural Science Foundation of China (22061007, 22071036); Frontiers Science Center for Asymmetric Synthesis and Medicinal Molecules, Department of Education, Guizhou Province [Qianjiaohe KY number (2020)004]; The 10 Talent Plan (Shicengci) of Guizhou Province ([2016]5649); Science and Technology Department of Guizhou Province ([2018]2802, [2019]1020); Program of Introducing Talents of Discipline to Universities of China (111 Program, D20023) at Guizhou University; Singapore National Research Foundation under its NRF Investigatorship (NRF-NRFI2016-06) and Competitive Research Program (NRF-CRP22-2019-0002); and Ministry of Education, Singapore, under its MOE AcRF Tier 1 Award (RG7/20, RG5/19), MOE AcRF Tier 2 (MOE2019-T2-2-117), and MOE AcRF Tier 3 Award (MOE2018-T3-1-003). 2023-09-12T06:37:30Z 2023-09-12T06:37:30Z 2022 Journal Article Lv, J., Jin, Z., Wang, H. & Chi, R. Y. (2022). N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions. ACS Sustainable Chemistry and Engineering, 10(42), 13901-13916. https://dx.doi.org/10.1021/acssuschemeng.2c03868 2168-0485 https://hdl.handle.net/10356/170452 10.1021/acssuschemeng.2c03868 2-s2.0-85140861585 42 10 13901 13916 en NRF-NRFI2016-06 NRF-CRP22-2019-0002 RG7/20 RG5/19 MOE2019-T2-2-117 MOE2018-T3-1-003 ACS Sustainable Chemistry and Engineering © 2022 American Chemical Society. All rights reserved.
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic Science::Chemistry
Carbon-Sulfur Bond Formation
N-Heterocyclic Carbene
spellingShingle Science::Chemistry
Carbon-Sulfur Bond Formation
N-Heterocyclic Carbene
Lv, Jie
Jin, Zhichao
Wang, Hongling
Chi, Robin Yonggui
N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions
description The carbon-sulfur (C-S) bond formation reactions enabled by N-heterocyclic carbene (NHC) organocatalysis are systematically summarized in this review. Diverse transformations involving NHC-catalyzed S-esterification, NHC-catalyzed nucleophilic S-conjugate addition, NHC-catalyzed S-addition reactions with electrophiles, and C-S bond formations via cooperative NHC/transition metal-catalyzed radical reactions are introduced and discussed. Our own comprehension and perspectives on this highly active research field are also provided at the end of this review.
author2 School of Physical and Mathematical Sciences
author_facet School of Physical and Mathematical Sciences
Lv, Jie
Jin, Zhichao
Wang, Hongling
Chi, Robin Yonggui
format Article
author Lv, Jie
Jin, Zhichao
Wang, Hongling
Chi, Robin Yonggui
author_sort Lv, Jie
title N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions
title_short N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions
title_full N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions
title_fullStr N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions
title_full_unstemmed N-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions
title_sort n-heterocyclic carbene-mediated carbon-sulfur bond-forming reactions
publishDate 2023
url https://hdl.handle.net/10356/170452
_version_ 1779156578779267072

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