Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes

Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes

The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80 is liberated by simple treatment of complex (Rp)-79...

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Bibliographic Details
Main Author: Lim, Maricar Bungabong
Other Authors: Leung Pak Hing
Format: Theses and Dissertations
Language:English
Published: 2009
Subjects:
DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:https://hdl.handle.net/10356/20676
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Institution: Nanyang Technological University
Language: English
Description
Summary:The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80 is liberated by simple treatment of complex (Rp)-79 with aqueous potassium cyanide.

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