Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes

The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80 is liberated by simple treatment of complex (Rp)-79...

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Main Author:	Lim, Maricar Bungabong
Other Authors:	Leung Pak Hing
Format:	Theses and Dissertations
Language:	English
Published:	2009
Subjects:	DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
Online Access:	https://hdl.handle.net/10356/20676
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Institution:	Nanyang Technological University
Language:	English

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spelling	sg-ntu-dr.10356-206762023-02-28T23:57:05Z Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes Lim, Maricar Bungabong Leung Pak Hing School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80 is liberated by simple treatment of complex (Rp)-79 with aqueous potassium cyanide. DOCTOR OF PHILOSOPHY (SPMS) 2009-12-23T05:57:19Z 2009-12-23T05:57:19Z 2008 2008 Thesis Lim, M. B. (2008). Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/20676 10.32657/10356/20676 en 283 p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
spellingShingle	DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds Lim, Maricar Bungabong Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
description	The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80 is liberated by simple treatment of complex (Rp)-79 with aqueous potassium cyanide.
author2	Leung Pak Hing
author_facet	Leung Pak Hing Lim, Maricar Bungabong
format	Theses and Dissertations
author	Lim, Maricar Bungabong
author_sort	Lim, Maricar Bungabong
title	Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
title_short	Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
title_full	Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
title_fullStr	Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
title_full_unstemmed	Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
title_sort	asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes
publishDate	2009
url	https://hdl.handle.net/10356/20676
_version_	1759857682379964416

Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes

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