Asymmetric synthesis of chiral arsine ligands promoted by organopalladium complexes

• Main Author: Lim, Maricar Bungabong
• Other Authors: Leung Pak Hing
• Format: Theses and Dissertations
• Language: English
• Published: 2009
• Subjects: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis; DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• Online Access: https://hdl.handle.net/10356/20676
• Institution: Nanyang Technological University

The bis(acetonitrile) (S) phenanthrylamine palladium II complex (Sc)-116 is used in the [4+2] Diels-Alder cycloaddition reaction between diphenylvinylarsine and DMPP producing two isomeric products in a ratio of 5:1. The bidentate ligand (Sp)-80 is liberated by simple treatment of complex (Rp)-79...