Formation of novel polycyclic P-S-P linked complex through an unexpected stepwise [4+4] cycloaddition.

• 主要作者: Lin, Yu Han.
• 其他作者: School of Physical and Mathematical Sciences
• 格式: Final Year Project
• 語言: English
• 出版: 2010
• 主題: DRNTU::Science::Chemistry::Organic chemistry::Organometallic compounds
• 在線閱讀: http://hdl.handle.net/10356/39408
• 機構: Nanyang Technological University

In this project we wish to report our findings on the synthesis of a P-S-P linked bidentate ligand, compound 1 from the precursor, bis[(3,4-dimethylphosphole) pentacarbonyltungsten]sulfide, 2. While in the preparation of compound 2, it was discovered that undergoes a [2+2] cycloaddition to form 3, f...