Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes

In 2000, List and co-workers firstly reported that L-proline was an effective asymmetric catalyst for the direct aldol reaction between unmodified acetone an a variety of aldehydes, with yields and enantioselectivities from moderate to good. This discovery has initiated the explosive growth of resea...

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Main Author: Zhu, Di
Other Authors: Zhong Guofu
Format: Theses and Dissertations
Language:English
Published: 2011
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Online Access:http://hdl.handle.net/10356/46316
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-463162023-02-28T23:53:00Z Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes Zhu, Di Zhong Guofu School of Physical and Mathematical Sciences DRNTU::Science In 2000, List and co-workers firstly reported that L-proline was an effective asymmetric catalyst for the direct aldol reaction between unmodified acetone an a variety of aldehydes, with yields and enantioselectivities from moderate to good. This discovery has initiated the explosive growth of research activities in organic chemistry. Now asymmetric organo-catalysis in which small chiral organic molecules act as catalytically active species, emerged as powerful synthetic tool and are complementary to transition metal based catalysis and biocatalysis in asymmetric synthesis. ​Master of Science 2011-11-30T03:13:42Z 2011-11-30T03:13:42Z 2011 2011 Thesis http://hdl.handle.net/10356/46316 en 83 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Science
spellingShingle DRNTU::Science
Zhu, Di
Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes
description In 2000, List and co-workers firstly reported that L-proline was an effective asymmetric catalyst for the direct aldol reaction between unmodified acetone an a variety of aldehydes, with yields and enantioselectivities from moderate to good. This discovery has initiated the explosive growth of research activities in organic chemistry. Now asymmetric organo-catalysis in which small chiral organic molecules act as catalytically active species, emerged as powerful synthetic tool and are complementary to transition metal based catalysis and biocatalysis in asymmetric synthesis.
author2 Zhong Guofu
author_facet Zhong Guofu
Zhu, Di
format Theses and Dissertations
author Zhu, Di
author_sort Zhu, Di
title Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes
title_short Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes
title_full Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes
title_fullStr Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes
title_full_unstemmed Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes
title_sort highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes
publishDate 2011
url http://hdl.handle.net/10356/46316
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