Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes
In 2000, List and co-workers firstly reported that L-proline was an effective asymmetric catalyst for the direct aldol reaction between unmodified acetone an a variety of aldehydes, with yields and enantioselectivities from moderate to good. This discovery has initiated the explosive growth of resea...
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sg-ntu-dr.10356-463162023-02-28T23:53:00Z Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes Zhu, Di Zhong Guofu School of Physical and Mathematical Sciences DRNTU::Science In 2000, List and co-workers firstly reported that L-proline was an effective asymmetric catalyst for the direct aldol reaction between unmodified acetone an a variety of aldehydes, with yields and enantioselectivities from moderate to good. This discovery has initiated the explosive growth of research activities in organic chemistry. Now asymmetric organo-catalysis in which small chiral organic molecules act as catalytically active species, emerged as powerful synthetic tool and are complementary to transition metal based catalysis and biocatalysis in asymmetric synthesis. Master of Science 2011-11-30T03:13:42Z 2011-11-30T03:13:42Z 2011 2011 Thesis http://hdl.handle.net/10356/46316 en 83 p. application/pdf |
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DRNTU::Science Zhu, Di Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes |
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In 2000, List and co-workers firstly reported that L-proline was an effective asymmetric catalyst for the direct aldol reaction between unmodified acetone an a variety of aldehydes, with yields and enantioselectivities from moderate to good. This discovery has initiated the explosive growth of research activities in organic chemistry. Now asymmetric organo-catalysis in which small chiral organic molecules act as catalytically active species, emerged as powerful synthetic tool and are complementary to transition metal based catalysis and biocatalysis in asymmetric synthesis. |
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Zhong Guofu |
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Zhong Guofu Zhu, Di |
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Theses and Dissertations |
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Zhu, Di |
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Zhu, Di |
title |
Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes |
title_short |
Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes |
title_full |
Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes |
title_fullStr |
Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes |
title_full_unstemmed |
Highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes |
title_sort |
highly stereoselective synthesis of tetrahydro-1,2-oxazines and bicyclic isoxazolidines from nitroso benzenes and 5-alkenylaldehydes |
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2011 |
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http://hdl.handle.net/10356/46316 |
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