Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines

The catalytic hydroamination of alkenes provides an efficient and direct entry to synthetically useful amines. An efficient method for the hydroamination between non-activated alkenes and aniline catalyzed by the system of Pr(OTf)3/n-Bu4PI/I2 was developed. Allylamines are important building blocks...

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Main Author:	Yin, Peng
Other Authors:	Loh Teck Peng
Format:	Theses and Dissertations
Language:	English
Published:	2012
Subjects:	DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Online Access:	https://hdl.handle.net/10356/48065
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Institution:	Nanyang Technological University
Language:	English

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spelling	sg-ntu-dr.10356-480652023-02-28T23:54:34Z Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines Yin, Peng Loh Teck Peng School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis The catalytic hydroamination of alkenes provides an efficient and direct entry to synthetically useful amines. An efficient method for the hydroamination between non-activated alkenes and aniline catalyzed by the system of Pr(OTf)3/n-Bu4PI/I2 was developed. Allylamines are important building blocks in organic synthesis, and are also used as starting materials for the synthesis of many compounds such as amino acids, and different alkaloids. Two catalytic systems for the allylic amination with aqueous ammonia and ammonia gas were well-developed. DOCTOR OF PHILOSOPHY (SPMS) 2012-03-01T01:36:45Z 2012-03-01T01:36:45Z 2011 2011 Thesis Yin, P. (2011). Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/48065 10.32657/10356/48065 en 142 p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
spellingShingle	DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis Yin, Peng Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines
description	The catalytic hydroamination of alkenes provides an efficient and direct entry to synthetically useful amines. An efficient method for the hydroamination between non-activated alkenes and aniline catalyzed by the system of Pr(OTf)3/n-Bu4PI/I2 was developed. Allylamines are important building blocks in organic synthesis, and are also used as starting materials for the synthesis of many compounds such as amino acids, and different alkaloids. Two catalytic systems for the allylic amination with aqueous ammonia and ammonia gas were well-developed.
author2	Loh Teck Peng
author_facet	Loh Teck Peng Yin, Peng
format	Theses and Dissertations
author	Yin, Peng
author_sort	Yin, Peng
title	Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines
title_short	Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines
title_full	Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines
title_fullStr	Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines
title_full_unstemmed	Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines
title_sort	part i: intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. part ii: nhc-pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines
publishDate	2012
url	https://hdl.handle.net/10356/48065
_version_	1759857290154868736

Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines

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