Part I: Intermolecular hydroamination between nonactivated alkenes and aniline catalyzed by lanthanide salts in ionic solvents. Part II: NHC-Pd complex catalyzed allylic amination using ammonia for the synthesis of primary amines

• المؤلف الرئيسي: Yin, Peng
• مؤلفون آخرون: Loh Teck Peng
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2012
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/48065
• المؤسسة: Nanyang Technological University

The catalytic hydroamination of alkenes provides an efficient and direct entry to synthetically useful amines. An efficient method for the hydroamination between non-activated alkenes and aniline catalyzed by the system of Pr(OTf)3/n-Bu4PI/I2 was developed. Allylamines are important building blocks...