Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions

Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions

The first part of this thesis aims to provide an account of the synthetic strategies employed for the asymmetric formation of novel ferrocenyl monophosphine ligands. It also attempts to justify the observed stereoselectivities with mechanistic models. Following which, the second part of the thesis c...

Full description

Saved in:
Bibliographic Details
Main Author: Gan, Kennard Jun Hao
Other Authors: Pullarkat Appukuttan Sumod
Format: Theses and Dissertations
Language:English
Published: 2016
Subjects:
DRNTU::Science::Chemistry::Inorganic chemistry::Metals
DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Online Access:https://hdl.handle.net/10356/65930
Tags: Add Tag
No Tags, Be the first to tag this record!
Institution: Nanyang Technological University
Language: English
Description
Summary:The first part of this thesis aims to provide an account of the synthetic strategies employed for the asymmetric formation of novel ferrocenyl monophosphine ligands. It also attempts to justify the observed stereoselectivities with mechanistic models. Following which, the second part of the thesis comprises the successful application of cyclometalated Palladium(II)-complexes as catalysts toward aryl boronic acid addition onto a variety of unsaturated enones.

Similar Items