Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions

• Main Author: Gan, Kennard Jun Hao
• Other Authors: Pullarkat Appukuttan Sumod
• Format: Theses and Dissertations
• Language: English
• Published: 2016
• Subjects: DRNTU::Science::Chemistry::Inorganic chemistry::Metals; DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
• Online Access: https://hdl.handle.net/10356/65930
• Institution: Nanyang Technological University

The first part of this thesis aims to provide an account of the synthetic strategies employed for the asymmetric formation of novel ferrocenyl monophosphine ligands. It also attempts to justify the observed stereoselectivities with mechanistic models. Following which, the second part of the thesis c...