Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions

Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions

The first part of this thesis aims to provide an account of the synthetic strategies employed for the asymmetric formation of novel ferrocenyl monophosphine ligands. It also attempts to justify the observed stereoselectivities with mechanistic models. Following which, the second part of the thesis c...

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Main Author: Gan, Kennard Jun Hao
Other Authors: Pullarkat Appukuttan Sumod
Format: Theses and Dissertations
Language:English
Published: 2016
Subjects:
DRNTU::Science::Chemistry::Inorganic chemistry::Metals
DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Online Access:https://hdl.handle.net/10356/65930
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Institution: Nanyang Technological University
Language: English
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spelling sg-ntu-dr.10356-659302023-02-28T23:46:57Z Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions Gan, Kennard Jun Hao Pullarkat Appukuttan Sumod Leung Pak Hing School of Physical and Mathematical Sciences DRNTU::Science::Chemistry::Inorganic chemistry::Metals DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis The first part of this thesis aims to provide an account of the synthetic strategies employed for the asymmetric formation of novel ferrocenyl monophosphine ligands. It also attempts to justify the observed stereoselectivities with mechanistic models. Following which, the second part of the thesis comprises the successful application of cyclometalated Palladium(II)-complexes as catalysts toward aryl boronic acid addition onto a variety of unsaturated enones. DOCTOR OF PHILOSOPHY (SPMS) 2016-01-29T02:41:48Z 2016-01-29T02:41:48Z 2016 Thesis Gan, K. J. H. (2016). Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions. Doctoral thesis, Nanyang Technological University, Singapore. https://hdl.handle.net/10356/65930 10.32657/10356/65930 en 224 p. application/pdf
institution Nanyang Technological University
building NTU Library
continent Asia
country Singapore
Singapore
content_provider NTU Library
collection DR-NTU
language English
topic DRNTU::Science::Chemistry::Inorganic chemistry::Metals
DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
spellingShingle DRNTU::Science::Chemistry::Inorganic chemistry::Metals
DRNTU::Science::Chemistry::Organic chemistry::Organic synthesis
Gan, Kennard Jun Hao
Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions
description The first part of this thesis aims to provide an account of the synthetic strategies employed for the asymmetric formation of novel ferrocenyl monophosphine ligands. It also attempts to justify the observed stereoselectivities with mechanistic models. Following which, the second part of the thesis comprises the successful application of cyclometalated Palladium(II)-complexes as catalysts toward aryl boronic acid addition onto a variety of unsaturated enones.
author2 Pullarkat Appukuttan Sumod
author_facet Pullarkat Appukuttan Sumod
Gan, Kennard Jun Hao
format Theses and Dissertations
author Gan, Kennard Jun Hao
author_sort Gan, Kennard Jun Hao
title Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions
title_short Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions
title_full Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions
title_fullStr Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions
title_full_unstemmed Cyclometalated palladium(II)-catalyzed asymmetric C-C and C-P bond formation reactions
title_sort cyclometalated palladium(ii)-catalyzed asymmetric c-c and c-p bond formation reactions
publishDate 2016
url https://hdl.handle.net/10356/65930
_version_ 1759855827450068992

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