Synthesis and reactivities of novel divalent group 14 elements species

• المؤلف الرئيسي: Wang, Liliang
• مؤلفون آخرون: Kinjo Rei
• التنسيق: Theses and Dissertations
• اللغة: English
• منشور في: 2018
• الموضوعات: DRNTU::Science::Chemistry::Organic chemistry
• الوصول للمادة أونلاين: http://hdl.handle.net/10356/73513

In this thesis, we have first synthesized a cyclic (alkyl)(amino) germylene (CAAGe) which possesses the high-lying HOMO−1 and low-lying LUMO, which was supported by DFT calculations. The reactivities have been investigated subsequently. The reaction of CAAGe with S8 was first carried out, where led...