Palladacycle Promoted Base Controlled Regio- and Enantioselective Hydrophosphination of 2-Pyridylacrylate/amide and the Cytotoxicity of their Gold Complexes
The regioselective asymmetric hydrophosphination of pyridine-functionalized alkenes can be achieved in the presence of stoichiometric amounts of the chiral palladium complex (R)-1. The presence or absence of base affords the respective β- and α-adducts with excellent regiocontrol. Chiral gold-phosph...
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| Main Authors: | , , , , , , , |
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| 格式: | Article |
| 語言: | English |
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2016
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| 主題: | |
| 在線閱讀: | https://hdl.handle.net/10356/81881 http://hdl.handle.net/10220/39745 |
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