Low temperature synthesis of sub-micrometer yttria-doped barium zirconate thin films by modified chemical solution deposition technique
Yttria-doped barium zirconate (BZY) electrolyte films with submicrometer thickness were prepared using a modified chemical solution deposition (CSD) technique at very low sintering temperature of 800°C without sintering aid. Pure perovskite BZY phase without barium carbonate associated with low calc...
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sg-ntu-dr.10356-828382023-03-04T17:14:10Z Low temperature synthesis of sub-micrometer yttria-doped barium zirconate thin films by modified chemical solution deposition technique Biswas, Mridula Xie, Hanlin Su, Pei-Chen School of Mechanical and Aerospace Engineering Deposition Low Temperature DRNTU::Engineering::Mechanical engineering Yttria-doped barium zirconate (BZY) electrolyte films with submicrometer thickness were prepared using a modified chemical solution deposition (CSD) technique at very low sintering temperature of 800°C without sintering aid. Pure perovskite BZY phase without barium carbonate associated with low calcination temperature was successfully obtained with no obvious barium (Ba) evaporation to deviate the stoichiometry composition. This cost effective and scalable method for BYZ, as compared to the other reported vacuum-based thin film deposition techniques such as pulsed laser deposition (PLD) or atomic layer deposition (ALD), is potentially applicable in the fabrication of high quality electrolyte for nano-thin film micro solid oxide fuel cells operating at temperature below 500°C. NRF (Natl Research Foundation, S’pore) MOE (Min. of Education, S’pore) Published version 2019-05-10T07:13:30Z 2019-12-06T15:06:38Z 2019-05-10T07:13:30Z 2019-12-06T15:06:38Z 2015 Journal Article Biswas, M., Xie, H., & Su, P.-C. (2015). Low temperature synthesis of sub-micrometer yttria-doped barium zirconate thin films by modified chemical solution deposition technique. ECS Transactions, 68(1), 481-488. doi:10.1149/06801.0481ecst 1938-5862 https://hdl.handle.net/10356/82838 http://hdl.handle.net/10220/48157 10.1149/06801.0481ecst en ECS Transactions © 2015 The Electrochemical Society. All rights reserved. This paper was published in ECS Transactions and is made available with permission of The Electrochemical Society. 8 p. application/pdf |
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Deposition Low Temperature DRNTU::Engineering::Mechanical engineering Biswas, Mridula Xie, Hanlin Su, Pei-Chen Low temperature synthesis of sub-micrometer yttria-doped barium zirconate thin films by modified chemical solution deposition technique |
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Yttria-doped barium zirconate (BZY) electrolyte films with submicrometer thickness were prepared using a modified chemical solution deposition (CSD) technique at very low sintering temperature of 800°C without sintering aid. Pure perovskite BZY phase without barium carbonate associated with low calcination temperature was successfully obtained with no obvious barium (Ba) evaporation to deviate the stoichiometry composition. This cost effective and scalable method for BYZ, as compared to the other reported vacuum-based thin film deposition techniques such as pulsed laser deposition (PLD) or atomic layer deposition (ALD), is potentially applicable in the fabrication of high quality electrolyte for nano-thin film micro solid oxide fuel cells operating at temperature below 500°C. |
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School of Mechanical and Aerospace Engineering |
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School of Mechanical and Aerospace Engineering Biswas, Mridula Xie, Hanlin Su, Pei-Chen |
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Article |
author |
Biswas, Mridula Xie, Hanlin Su, Pei-Chen |
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Biswas, Mridula |
title |
Low temperature synthesis of sub-micrometer yttria-doped barium zirconate thin films by modified chemical solution deposition technique |
title_short |
Low temperature synthesis of sub-micrometer yttria-doped barium zirconate thin films by modified chemical solution deposition technique |
title_full |
Low temperature synthesis of sub-micrometer yttria-doped barium zirconate thin films by modified chemical solution deposition technique |
title_fullStr |
Low temperature synthesis of sub-micrometer yttria-doped barium zirconate thin films by modified chemical solution deposition technique |
title_full_unstemmed |
Low temperature synthesis of sub-micrometer yttria-doped barium zirconate thin films by modified chemical solution deposition technique |
title_sort |
low temperature synthesis of sub-micrometer yttria-doped barium zirconate thin films by modified chemical solution deposition technique |
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2019 |
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https://hdl.handle.net/10356/82838 http://hdl.handle.net/10220/48157 |
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1759858221120487424 |