NHC-Ag/Pd-Catalyzed Reductive Carboxylation of Terminal Alkynes with CO2 and H2: A Combined Experimental and Computational Study for Fine-Tuned Selectivity

• المؤلفون الرئيسيون: Yu, Dingyi, Zhou, Feng, Lim, Diane S. W., Su, Haibin, Zhang, Yugen
• مؤلفون آخرون: School of Materials Science & Engineering
• التنسيق: مقال
• اللغة: English
• منشور في: 2017
• الموضوعات: Ag/Pd catalyst; CO2 utilization
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/83473; http://hdl.handle.net/10220/42622

Reductive carboxylation of terminal alkynes utilizing CO2 and H2 as reactants is an interesting and challenging transformation. Theoretical calculations indicated it would be kinetically possible to obtain cinnamic acid, the reductive carboxylation product, from phenylacetylene in a CO2/H2 system wi...