Investigation of Functional Group Effects on Palladium Catalysed Asymmetric P–H Addition

• المؤلفون الرئيسيون: Li, Xi-Rui, Chew, Renta Jonathan, Li, Yongxin, Leung, Pak-Hing
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2016
• الموضوعات: Catalysts; Phosphorus compounds
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/84714; http://hdl.handle.net/10220/41919

The pincer catalysed asymmetric P–H addition of diphenylphosphine to 3-benzylidene-2,4-pentadione is herein reported. Albeit successful in catalysing a series of similar substrates, unexpected chelation of the dione substrate to a CP and CN palladacycle catalyst resulted in inactivation of the catal...