Alkene–Carbene Isomerization induced by Borane: Access to an Asymmetrical Diborene

• Main Authors: Kinjo, Rei, Lu, Wei, Li, Yongxin, Ganguly, Rakesh
• Other Authors: School of Physical and Mathematical Sciences
• Format: Article
• Language: English
• Published: 2017
• Subjects: Diborene; Alkene-carbene isomerization
• Online Access: https://hdl.handle.net/10356/85146; http://hdl.handle.net/10220/43661
• Institution: Nanyang Technological University

A 2,3-dihydro-1H-1,2-azaborole derivative 2 was converted to a cyclic (alkyl) (amino)carbene (cAAC) via 1,2-hydrogen migration triggered by boranes to afford cAAC-borane adducts. This procedure allowed us to develop an asymmetrical diborene cAAC·(Br)B═B(Br)·IDip 6, which was isolated and fully chara...