Alkene–Carbene Isomerization induced by Borane: Access to an Asymmetrical Diborene
A 2,3-dihydro-1H-1,2-azaborole derivative 2 was converted to a cyclic (alkyl) (amino)carbene (cAAC) via 1,2-hydrogen migration triggered by boranes to afford cAAC-borane adducts. This procedure allowed us to develop an asymmetrical diborene cAAC·(Br)B═B(Br)·IDip 6, which was isolated and fully chara...
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| Main Authors: | , , , |
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| Other Authors: | |
| Format: | Article |
| Language: | English |
| Published: |
2017
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| Subjects: | |
| Online Access: | https://hdl.handle.net/10356/85146 http://hdl.handle.net/10220/43661 |
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| Institution: | Nanyang Technological University |
| Language: | English |