Access to P-Stereogenic Phosphinates via N-Heterocyclic Carbene-Catalyzed Desymmetrization of Bisphenols

Access to P-Stereogenic Phosphinates via N-Heterocyclic Carbene-Catalyzed Desymmetrization of Bisphenols

A carbene-catalyzed desymmetrization of prochiral bisphenol compounds bearing remote P-stereogenic centers is disclosed. The catalytic reactions can be performed on gram scales with 1 mol % N-heterocyclic carbene (NHC) catalyst, providing efficient access to enantiomerically enriched P-stereogenic p...

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Bibliographic Details
Main Authors: Huang, Zhijian, Huang, Xuan, Li, Baosheng, Mou, Chengli, Yang, Song, Song, Bao-An, Chi, Yonggui Robin
Other Authors: School of Physical and Mathematical Sciences
Format: Article
Language:English
Published: 2017
Subjects:
Bisphenols
Phosphinates
Online Access:https://hdl.handle.net/10356/85621
http://hdl.handle.net/10220/43779
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Institution: Nanyang Technological University
Language: English

Internet

https://hdl.handle.net/10356/85621
http://hdl.handle.net/10220/43779

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