Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates

A cobalt–N-heterocyclic carbene (NHC) catalyst efficiently promotes an ortho C–H alkenylation reaction of pivalophenone N–H imine with an alkenyl phosphate. The reaction tolerates various substituted pivalophenone N–H imines as well as cyclic and acyclic alkenyl phosphates.

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Main Authors:	Xu, Wengang, Yoshikai, Naohiko
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2018
Subjects:	C–C Bond Formation Alkenylation
Online Access:	https://hdl.handle.net/10356/86228 http://hdl.handle.net/10220/45244
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Institution:	Nanyang Technological University
Language:	English

id	sg-ntu-dr.10356-86228
record_format	dspace
spelling	sg-ntu-dr.10356-862282023-02-28T19:31:49Z Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates Xu, Wengang Yoshikai, Naohiko School of Physical and Mathematical Sciences C–C Bond Formation Alkenylation A cobalt–N-heterocyclic carbene (NHC) catalyst efficiently promotes an ortho C–H alkenylation reaction of pivalophenone N–H imine with an alkenyl phosphate. The reaction tolerates various substituted pivalophenone N–H imines as well as cyclic and acyclic alkenyl phosphates. MOE (Min. of Education, S’pore) Published version 2018-07-26T04:04:03Z 2019-12-06T16:18:31Z 2018-07-26T04:04:03Z 2019-12-06T16:18:31Z 2018 Journal Article Xu, W., & Yoshikai, N. (2018). Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates. Beilstein Journal of Organic Chemistry, 14, 709-715. 1860-5397 https://hdl.handle.net/10356/86228 http://hdl.handle.net/10220/45244 10.3762/bjoc.14.60 en Beilstein Journal of Organic Chemistry © 2018 Xu and Yoshikai; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc) 7 p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	C–C Bond Formation Alkenylation
spellingShingle	C–C Bond Formation Alkenylation Xu, Wengang Yoshikai, Naohiko Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
description	A cobalt–N-heterocyclic carbene (NHC) catalyst efficiently promotes an ortho C–H alkenylation reaction of pivalophenone N–H imine with an alkenyl phosphate. The reaction tolerates various substituted pivalophenone N–H imines as well as cyclic and acyclic alkenyl phosphates.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Xu, Wengang Yoshikai, Naohiko
format	Article
author	Xu, Wengang Yoshikai, Naohiko
author_sort	Xu, Wengang
title	Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title_short	Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title_full	Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title_fullStr	Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title_full_unstemmed	Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates
title_sort	cobalt-catalyzed directed c–h alkenylation of pivalophenone n–h imine with alkenyl phosphates
publishDate	2018
url	https://hdl.handle.net/10356/86228 http://hdl.handle.net/10220/45244
_version_	1759855814044024832

Cobalt-catalyzed directed C–H alkenylation of pivalophenone N–H imine with alkenyl phosphates

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