Crystalline boron-linked tetraaminoethylene radical cations
Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4˙+, which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized...
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sg-ntu-dr.10356-868282023-02-28T19:34:15Z Crystalline boron-linked tetraaminoethylene radical cations Su, Yuanting Li, Yongxin Ganguly, Rakesh Kinjo, Rei School of Physical and Mathematical Sciences Radical Cations Boron Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4˙+, which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized over the B2N4C2 skeleton and the spin density mainly resides on the carbon and boron atoms. MOE (Min. of Education, S’pore) Published version 2018-01-08T05:02:38Z 2019-12-06T16:29:46Z 2018-01-08T05:02:38Z 2019-12-06T16:29:46Z 2017 Journal Article Su, Y., Li, Y., Ganguly, R., & Kinjo, R. (2017). Crystalline boron-linked tetraaminoethylene radical cations. Chemical Science, 8(11), 7419-7423. 2041-6520 https://hdl.handle.net/10356/86828 http://hdl.handle.net/10220/44257 10.1039/C7SC03528D en Chemical Science © 2017 The Author(s) (published by Royal Society of Chemistry). This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. 5 p. application/pdf |
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Radical Cations Boron |
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Radical Cations Boron Su, Yuanting Li, Yongxin Ganguly, Rakesh Kinjo, Rei Crystalline boron-linked tetraaminoethylene radical cations |
| description |
Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4˙+, which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized over the B2N4C2 skeleton and the spin density mainly resides on the carbon and boron atoms. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Su, Yuanting Li, Yongxin Ganguly, Rakesh Kinjo, Rei |
| format |
Article |
| author |
Su, Yuanting Li, Yongxin Ganguly, Rakesh Kinjo, Rei |
| author_sort |
Su, Yuanting |
| title |
Crystalline boron-linked tetraaminoethylene radical cations |
| title_short |
Crystalline boron-linked tetraaminoethylene radical cations |
| title_full |
Crystalline boron-linked tetraaminoethylene radical cations |
| title_fullStr |
Crystalline boron-linked tetraaminoethylene radical cations |
| title_full_unstemmed |
Crystalline boron-linked tetraaminoethylene radical cations |
| title_sort |
crystalline boron-linked tetraaminoethylene radical cations |
| publishDate |
2018 |
| url |
https://hdl.handle.net/10356/86828 http://hdl.handle.net/10220/44257 |
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1759858081768931328 |