Crystalline boron-linked tetraaminoethylene radical cations

• المؤلفون الرئيسيون: Su, Yuanting, Li, Yongxin, Ganguly, Rakesh, Kinjo, Rei
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2018
• الموضوعات: Radical Cations; Boron
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/86828; http://hdl.handle.net/10220/44257

Single-electron oxidation of neutral boryl-linked tetraaminoethylene derivatives 4 led to the formation of radical cations 4˙+, which have been isolated and fully characterized. X-ray diffraction analysis, EPR spectroscopy, and computational studies revealed that the unpaired electron is delocalized...