Mechanistic insights for the photoredox organocatalytic fluorination of aliphatic carbons by anthraquinone using time-resolved and DFT studies

• المؤلفون الرئيسيون: Kee, J. W., Shao, H., Kee, C. W., Lu, Yunpeng, Soo, Han Sen, Tan, Choon Hong
• مؤلفون آخرون: School of Physical and Mathematical Sciences
• التنسيق: مقال
• اللغة: English
• منشور في: 2018
• الموضوعات: Photoredox Catalysis; C-H Fluorination; DRNTU::Science::Chemistry
• الوصول للمادة أونلاين: https://hdl.handle.net/10356/87664; http://hdl.handle.net/10220/47035
• المؤسسة: Nanyang Technological University

Chemoselective photoredox fluorination is an appealing approach to access fluorinated fine chemicals such as active pharmaceutical ingredients, but most of the known procedures currently lack time-resolved mechanistic insights. We use nanosecond transient absorption spectroscopy and density function...