Isolation of a cyclic (alkyl)(amino)germylene

A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO...

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Main Authors:	Wang, Liliang, Li, Yongxin, Ganguly, Rakesh, Kinjo, Rei, Lim, Yi Shan
Other Authors:	School of Physical and Mathematical Sciences
Format:	Article
Language:	English
Published:	2018
Subjects:	Germylene Low-valent Germanium DRNTU::Science::Chemistry
Online Access:	https://hdl.handle.net/10356/89591 http://hdl.handle.net/10220/46279
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Institution:	Nanyang Technological University
Language:	English

id	sg-ntu-dr.10356-89591
record_format	dspace
spelling	sg-ntu-dr.10356-895912023-02-28T19:36:43Z Isolation of a cyclic (alkyl)(amino)germylene Wang, Liliang Li, Yongxin Ganguly, Rakesh Kinjo, Rei Lim, Yi Shan School of Physical and Mathematical Sciences Germylene Low-valent Germanium DRNTU::Science::Chemistry A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively. MOE (Min. of Education, S’pore) Published version 2018-10-11T04:56:08Z 2019-12-06T17:29:07Z 2018-10-11T04:56:08Z 2019-12-06T17:29:07Z 2016 Journal Article Wang, L., Lim, Y. S., Li, Y., Ganguly, R., & Kinjo, R. (2016). Isolation of a cyclic (alkyl)(amino)germylene. Molecules, 21(8), 990-. doi:10.3390/molecules21080990 1420-3049 https://hdl.handle.net/10356/89591 http://hdl.handle.net/10220/46279 10.3390/molecules21080990 en Molecules © 2016 by the authors; licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC-BY) license (http://creativecommons.org/licenses/by/4.0/). 11 p. application/pdf
institution	Nanyang Technological University
building	NTU Library
continent	Asia
country	Singapore Singapore
content_provider	NTU Library
collection	DR-NTU
language	English
topic	Germylene Low-valent Germanium DRNTU::Science::Chemistry
spellingShingle	Germylene Low-valent Germanium DRNTU::Science::Chemistry Wang, Liliang Li, Yongxin Ganguly, Rakesh Kinjo, Rei Lim, Yi Shan Isolation of a cyclic (alkyl)(amino)germylene
description	A 1,4-addition of a dichlorogermylene dioxane complex with α,β-unsaturated imine 1 gave a dichlorogermane derivative 2 bearing a GeC3N five-membered ring skeleton. By reducing 2 with KC8, cyclic (alkyl)(amino)germylene 3 was synthesized and fully characterized. Germylene 3 readily reacted with TEMPO, N2O and S8, producing the 1:2 adduct 4, the oxo-bridged dimer 5 and the sulfido-bridged dimer 6, respectively.
author2	School of Physical and Mathematical Sciences
author_facet	School of Physical and Mathematical Sciences Wang, Liliang Li, Yongxin Ganguly, Rakesh Kinjo, Rei Lim, Yi Shan
format	Article
author	Wang, Liliang Li, Yongxin Ganguly, Rakesh Kinjo, Rei Lim, Yi Shan
author_sort	Wang, Liliang
title	Isolation of a cyclic (alkyl)(amino)germylene
title_short	Isolation of a cyclic (alkyl)(amino)germylene
title_full	Isolation of a cyclic (alkyl)(amino)germylene
title_fullStr	Isolation of a cyclic (alkyl)(amino)germylene
title_full_unstemmed	Isolation of a cyclic (alkyl)(amino)germylene
title_sort	isolation of a cyclic (alkyl)(amino)germylene
publishDate	2018
url	https://hdl.handle.net/10356/89591 http://hdl.handle.net/10220/46279
_version_	1759853890670428160

Isolation of a cyclic (alkyl)(amino)germylene

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