Electronic mechanism of critical temperature variation in RBa2Cu3O7−δ

We have performed systematic studies of the trend of the critical temperature Tc due to both Madelung site potential difference between in-plane oxygen and copper sites ΔVM and interlayer effect in the optimally doped 123 superconductors RBa2Cu3O7−δ. ΔVM is found to decrease with the i...

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Main Authors: Chen, Xiao Jia, Su, Haibin
其他作者: School of Materials Science & Engineering
格式: Article
語言:English
出版: 2011
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在線閱讀:https://hdl.handle.net/10356/93915
http://hdl.handle.net/10220/6929
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機構: Nanyang Technological University
語言: English
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總結:We have performed systematic studies of the trend of the critical temperature Tc due to both Madelung site potential difference between in-plane oxygen and copper sites ΔVM and interlayer effect in the optimally doped 123 superconductors RBa2Cu3O7−δ. ΔVM is found to decrease with the increase of the trivalent rare-earth ionic radius rR3+. This change enhances the next-nearest-neighbor hopping integral t', which results in the experimentally observed increase of Tc with rR3+. The coherent interlayer single-particle hopping t⊥ has a more profound effect than t' on the nearly linear trend of Tc as a function of rR3+. These results reveal the importance of the electronic origin of the rare-earth ionic size effect on Tc in this family.