Selective catalytic sp3 C–O bond cleavage with C–N bond formation in 3-alkoxy-1-propanols

The ruthenium catalyzed selective sp3 C–O cleavage with amide formation was reported in reactions of 3-alkoxy-1-propanol derivatives and amines. The cleavage only occurs at the C3–O position even with 3-benzyloxy-1-propanol. Based on the experimental results, O-bound and C-bound Ru enolate complexes...

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Main Authors: Chen, Cheng, Hong, Soon Hyeok
其他作者: School of Physical and Mathematical Sciences
格式: Article
語言:English
出版: 2013
在線閱讀:https://hdl.handle.net/10356/97360
http://hdl.handle.net/10220/10607
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機構: Nanyang Technological University
語言: English