Copper-catalyzed aminooxygenation of N-allylamidines with PhI(OAc)2
A Cu-catalyzed aminoacetoxylation of N-alkenylamidines has been achieved using PhI(OAc)2 as an oxygen source for synthesis of 4-acetoxymethyl-4,5-dihydroimidazoles, which could be further converted into 2,3-diaminopropanol derivatives using AlH3 as a reductant.
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2013
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sg-ntu-dr.10356-975202020-03-07T12:34:44Z Copper-catalyzed aminooxygenation of N-allylamidines with PhI(OAc)2 Sanjaya, Stephen Chiba, Shunsuke School of Physical and Mathematical Sciences A Cu-catalyzed aminoacetoxylation of N-alkenylamidines has been achieved using PhI(OAc)2 as an oxygen source for synthesis of 4-acetoxymethyl-4,5-dihydroimidazoles, which could be further converted into 2,3-diaminopropanol derivatives using AlH3 as a reductant. 2013-06-25T06:30:27Z 2019-12-06T19:43:31Z 2013-06-25T06:30:27Z 2019-12-06T19:43:31Z 2012 2012 Journal Article Sanjaya, S., & Chiba, S. (2012). Copper-Catalyzed Aminooxygenation of N-Allylamidines with PhI(OAc)2. Organic Letters, 14(20), 5342-5345. 1523-7060 https://hdl.handle.net/10356/97520 http://hdl.handle.net/10220/10632 10.1021/ol302525m en Organic letters © 2012 American Chemical Society. |
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A Cu-catalyzed aminoacetoxylation of N-alkenylamidines has been achieved using PhI(OAc)2 as an oxygen source for synthesis of 4-acetoxymethyl-4,5-dihydroimidazoles, which could be further converted into 2,3-diaminopropanol derivatives using AlH3 as a reductant. |
| author2 |
School of Physical and Mathematical Sciences |
| author_facet |
School of Physical and Mathematical Sciences Sanjaya, Stephen Chiba, Shunsuke |
| format |
Article |
| author |
Sanjaya, Stephen Chiba, Shunsuke |
| spellingShingle |
Sanjaya, Stephen Chiba, Shunsuke Copper-catalyzed aminooxygenation of N-allylamidines with PhI(OAc)2 |
| author_sort |
Sanjaya, Stephen |
| title |
Copper-catalyzed aminooxygenation of N-allylamidines with PhI(OAc)2 |
| title_short |
Copper-catalyzed aminooxygenation of N-allylamidines with PhI(OAc)2 |
| title_full |
Copper-catalyzed aminooxygenation of N-allylamidines with PhI(OAc)2 |
| title_fullStr |
Copper-catalyzed aminooxygenation of N-allylamidines with PhI(OAc)2 |
| title_full_unstemmed |
Copper-catalyzed aminooxygenation of N-allylamidines with PhI(OAc)2 |
| title_sort |
copper-catalyzed aminooxygenation of n-allylamidines with phi(oac)2 |
| publishDate |
2013 |
| url |
https://hdl.handle.net/10356/97520 http://hdl.handle.net/10220/10632 |
| _version_ |
1681044048610066432 |